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nydus/The Principles of Chemistry, Volume IPublic
Page 356 of 835
Table of Contents
16

Gas delivery tubes are usually made of glass tubing of various diameters and thicknesses. If of small diameter and thickness, a glass tube is easily bent by heating in a gas jet or the flame of a spirit lamp, and it may also be easily divided at a given point by making a deep scratch with a file and then breaking the tube at this point with a sharp jerk. These properties, together with their impermeability, transparency, hardness, and regularity of bore, render glass tubes most useful in experiments with gases. Naturally they might be replaced by straws, india-rubber, metallic, or other tubes, but these are more difficult to fix on to a vessel, and are not entirely impervious to gases. A glass gas delivery tube may be hermetically fixed into a vessel by fitting it into a perforated cork, which should be soft and free from flaws, and fixing the cork into the orifice of the vessel. To protect the cork from the action of gases it is sometimes previously soaked in paraffin, or it may be replaced by an india-rubber cork.

17

Gases, like all other substances, may be weighed, but, owing to their extreme lightness and the difficulty of dealing with them in large masses, they can only be weighed by very sensitive balances; that is, in such as, with a considerable load, indicate a very small difference in weight—for example, a centigram or a milligram with a load of 1,000 grams. In order to weigh a gas, a glass globe furnished with a tight-fitting stop-cock is first of all exhausted of air by an air-pump (a Sprengel pump is the best). The stop-cock is then closed, and the exhausted globe weighed. If the gas to be weighed is then let into the globe, its weight can be determined from the increase in the weight of the globe. It is necessary, however, that the temperature and pressure of the air about the balance should remain constant for both weighings, as the weight of the globe in air will (according to the laws of hydrostatics) vary with its density. The volume of the air displaced, and its weight, must therefore be determined by observing the temperature, density, and moisture of the atmosphere during the time of experiment. This will be partly explained later, but may be studied more in detail by physics. Owing to the complexity of all these operations, the mass of a gas is usually determined from its volume and density, or from the weight of a known volume.

18

The copper carbonate should be dried before weighing, as otherwise—besides copper oxide and carbonic anhydride—water will be obtained in the decomposition. Water forms a part of the composition of malachite, and has therefore to be taken into consideration. The water produced in the decomposition may be all collected by absorbing it in sulphuric acid or calcium chloride, as will be described further on. In order to dry a salt it must be heated at about 100° until its weight remains constant, or be placed under an air pump over sulphuric acid, as will also be presently described. As water is met with almost everywhere, and as it is absorbed by many substances, the possibility of its presence should never be lost sight of.

19

As the decomposition of red oxide of mercury requires so high a temperature, near redness, as to soften ordinary glass, it is necessary for this experiment to take a retort (or test tube) made of hard glass, which is able to stand high temperatures without softening. For the same reason, the lamp used must give a strong heat and a large flame, capable of embracing the whole bottom of the retort, which should be as small as possible for the convenience of the experiment.

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