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nydus/The Theory of Heat RadiationPublic
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Page 146 of 236
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128.

Let us then take N similar monatomic gas molecules in an arbitrarily given thermodynamic state and try to find the corresponding entropy. The state space is six-dimensional, with the three coordinates x, y, z, and the three corresponding moments mξ, mη, mζ, of a molecule, where we denote the mass by m and velocity components by ξ, η, ζ. Hence these quantities are to be substituted for the ϕ and ψ in [sect:126.] Sec. 126. We thus obtain for the size of a region element G the sextuple integral G=m3∫dσ,\Label[eqn](176)\upshape (176) where, for brevity dxdydzdξdηdζ=dσ.\Label[eqn](177)\upshape (177)

If the region elements are known, then, since the macroscopic state of the system of molecules was assumed as known, the numbers N1, N2, N3, … of the molecules which lie in the separate region elements are also known, and hence the distribution densities w1, w2, w3, … [eqn:(166)] (166) are given and the entropy of the state follows at once from [eqn:(173)] (173).

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