Herschell, who ascertained the relative intensity of the different coloured rays by illuminating objects under the microscope by their means, &c.
"Another certain proof of the difference in brightness of the different coloured rays is afforded by the phenomena of ocular spectra. If, after gazing at the sun, the eyes are closed so as to exclude the light, the image of the sun appears at first as a luminous or white spectrum upon a dark ground, but it gradually passes through the series of colours to black, that is to say, until it can no longer be distinguished from the dark field of vision; and the colours which it assumes are successively those intermediate between white and black in the order of their illuminating power or brightness, namely, yellow, orange, red, violet, and blue. If, on the other hand, after looking for some time at the sun we turn our eyes towards a white surface, the image of the sun is seen at first as a black spectrum upon the white surface, and gradually passes through the different colours from the darkest to the lightest, and at last becomes white, so that it can no longer be distinguished from the white surface"128—See par 40, 44.
It is not impossible that Aristotle's enumeration of the colours may have been derived from, or confirmed by, this very experiment. Speaking of the after-image of colours he says, "The impression not only exists in the sensorium in the act of perceiving, but remains when the organ is at rest. Thus if we look long and intently on any object, when we change the direction of the eyes a responding colour follows. If we look at the sun, or any other very bright object, and afterwards shut our eyes, we shall, as if in ordinary vision, first see a colour of the same kind; this will presently be changed to a red colour, then to purple, and so on till it ends in black and disappears."—De Insomniis.
NOTE N.—Par. 246.