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nydus/The Theory of Heat RadiationPublic
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Page 149 of 235
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131.

The values of the constants α and β may be found from those of V and E. For, on substituting the value of w just found in [eqn:(178)] (178) and taking account of [eqn:(177)] (177) and [eqn:(182)] (182), we get Gm3=αVeβ(ξ2+η2+ζ2)dξdηdζ=αV(πβ)32,

and on substituting w in [eqn:(181)] (181) we get

E=E0+αm4NV2G(ξ2+η2+ζ2)eβ(ξ2+η2+ζ2)dξdηdζ,

or

E=E0+3αm4NV4G1β(πβ)32.

Solving for α and β we have

α&=GV(3N4πm(EE0))32\Label[eqn](184)\upshape (184)β&=34NmEE0.\Label[eqn](185)\upshape (185)

From this finally we find, as an expression for the entropy S of the gas in the state of equilibrium with given values of N, V, and E, S=kNlog{VG(4πem(EE0)3N)32}.\Label[eqn](186)\upshape (186)

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