sulphuretted hydrogen (also named sulphurous acid), which is injurious to steel plates, and is largely responsible for the decay of tubes and funnels. More of the hydrogen unites with the oxygen as steam.
The most important element in coal is the carbon (known chemically by the symbol C). Its combination with oxygen, called combustion, is the act which heats the boiler. Only when the carbon present has combined with the greatest possible amount of oxygen that it will take into partnership is the combustion complete and the full heat-value (fixed by scientific experiment at 14,500 thermal units per pound of carbon) developed.
Now, carbon may unite with oxygen, atom for atom, and form carbon monoxide (CO); or in the proportion of one atom of carbon to two of oxygen, and form carbon dioxide (CO2). The former gas is combustible—that is, will admit another atom of carbon to the molecule—but the latter is saturated with oxygen, and will not burn, or, to put it otherwise, is the product of perfect combustion. A properly designed furnace, supplied with a due amount of air, will cause nearly all the carbon in the coal burnt to combine with the full amount of oxygen. On the other hand, if the oxygen supply is inefficient, CO as well as CO2 will form, and there will be a heat loss, equal in extreme cases to two-thirds of the whole. It is therefore necessary that a furnace which has to eat up fuel at a great pace should be artificially fed with air in the proportion of from 12 to 20 pounds of air for every pound of fuel. There are two methods of creating a violent draught through the furnace. The first is—
The forced draught; very simply exemplified by the ordinary bellows used in every house. On a ship (Fig. 10) the principle is developed as follows:—The boilers are situated in a compartment or compartments having no communication with the outer air, except for the passages down which air is forced by powerful fans at a pressure considerably greater than that of the atmosphere. There is only one "way out"—namely, through the furnace and tubes (or gas-ways) of the boiler, and the funnel. So through these it rushes, raising the fuel to white heat. As may easily be imagined, the temperature of a stokehold, especially in the tropics, is far from pleasant. In the Red Sea the thermometer sometimes rises to 170° Fahrenheit or more, and the poor stokers have a very bad time of it.