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CHAPTER XI. TRANSFORMATION PRODUCTS OF RADIUM.

readily be calculated that the equation of decay would be

Formula.

Taking the values of λ2 and λ3 found by Curie, the numerical factor

Formula.

becomes 2·15 instead of 4·3 and 1·15 instead of 3·3. The theoretical curve of decay in this case would be readily distinguishable from the observed curve of decay. The fact that the equation of decay found by Curie and Danne involves the necessity of an initial rayless change can be shown as follows:—

Curve I (Fig. 89) shows the experimental curve. At the moment of removal of the body from the emanation (disregarding the initial rapid change), the matter must consist of both B and C. Consider the matter which existed in the form C at the moment of removal. It will be transformed according to an exponential law, the activity falling by one-half in 28 minutes. This is shown in curve II. Curve III represents the difference between the ordinates of curves I and II. It will be seen that it is identical in shape with the curve (Fig. 87) showing the variation of the activity for a short exposure, measured by the β rays. It passes through a maximum at the same time (about 36 minutes). The explanation of such a curve is only possible on the assumption that the first change is a rayless one. The ordinates

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