CodalSearch this book — or all of Codal…⌘K
nydus/Radio-ActivityPublic
Page 481 of 609
Table of Contents

CHAPTER XIII. RADIO-ACTIVE PROCESSES.

the same arrangement of electrons as the group of 40 with the addition of an outer ring of 20 electrons; the group of 40 is the same as the group of 24 with an additional ring outside; and the group of 24 in turn is the same as the group of 11 with an extra ring. A series of model atoms may be formed in this way, in which each atom is derived from the preceding member by an additional ring of electrons. Such atoms would be expected to possess many properties in common, and would correspond to the elements in the same vertical column of the periodic table of Mendeléef.

Different arrangements of electrons vary widely in stability. Some may acquire an extra electron or two and yet remain stable, others readily lose an electron without disturbing their stability. The former would correspond to an electro-negative atom, the latter to an electro-positive.

Certain arrangements of electrons are stable if the electrons move with an angular velocity greater than a certain value, but become unstable when the velocity falls below this value. Four electrons in motion, for example, are stable in one plane, but when the velocity falls below a certain critical value, the system is unstable, and the electrons tend to arrange themselves at the corners of a regular tetrahedron. J. J. Thomson (loc. cit.) applies this property to explain why an atom of radio-active matter breaks up, as follows:—

“Consider now the properties of an atom containing a system of corpuscles (electrons) of this kind. Suppose the corpuscles were originally moving with velocities far exceeding the critical velocity; in consequence of the radiation from the moving corpuscles, their velocity will slowly—very slowly—diminish; when, after a long interval, the velocity reaches the critical velocity, there will be what is equivalent to an explosion of the corpuscles, the corpuscles will move far away from their original position, their potential energy will decrease, while their kinetic energy will increase. The kinetic energy gained in this way might be sufficient to carry the system out of the atom, and we should have, as in the case of radium, a part of the atom shot off. In consequence of the very slow dissipation of energy by radiation the life of the atom would be very long. We have taken the case of the four corpuscles as the type of a system which, like a top, requires for its stability a certain amount of rotation. Any system possessing this property would, in consequence of the gradual dissipation of energy by radiation, give to the atom containing it radio-active properties similar to those conferred by the four corpuscles.”

271. Heat of the sun and earth. It was pointed out by Rutherford and Soddy48 that the maintenance of the sun’s heat for long intervals of time did not present any fundamental difficulty if a process of disintegration, such as occurs in the radio-elements, were supposed to be taking place in the sun. In a letter to Nature (July 9, 1903) W. E. Wilson showed that the presence of 3·6 grams of radium in each cubic metre of the sun’s mass was sufficient to account for the present rate of emission of energy by the sun. This calculation was based on the estimate of Curie and Laborde that 1 gram of radium emits 100 gram-calories per hour, and on the observation of Langley that each square centimetre of the sun’s surface emits 8·28 × 106 gram-calories per hour. Since the average density of the sun is 1·44, the presence of radium in the sun, to the extent of 2·5 parts by weight in a million, would account for its present

481