273. Radio-activity of the atmosphere. The experiments of Geitel1 and C. T. R. Wilson2 in 1900 showed that a positively or negatively charged conductor placed inside a closed vessel gradually lost its charge. This loss of charge was shown to be due to a small ionization of the air inside the vessel. Elster and Geitel also found that a charged body exposed in the open air lost its charge rapidly, and that the rate of discharge was dependent on the locality and on atmospheric conditions. A more detailed description and discussion of these results will be given later in section 284.
In the course of these experiments, Geitel observed that the rate of discharge increased slightly for some time after the vessel had been closed. He considered that this might possibly be due to the existence of some radio-active substances in the air, which produced excited activity on the walls of the vessel and so increased the rate of dissipation of the charge. In 1901 Elster and Geitel3 tried the bold experiment of seeing whether it were possible to extract a radio-active substance from the air. The experiments of the writer had shown that the excited radio-activity from the thorium emanation could be concentrated on the negative electrode in a strong electric field. This result indicated that the carriers of the radio-activity had a positive charge of electricity. Elster and Geitel therefore tried an experiment to see whether positively charged carriers, possessing a similar property, were present in the atmosphere. For this purpose a cylinder of wire-netting, charged negatively to 600 volts, was exposed for several hours in the open air. The cylinder was then removed, and quickly placed in a large bell-jar, inside which was placed an electroscope to detect the rate of discharge. It was found that the rate of discharge was increased to a slight extent. In order to multiply the effect a wire about 20 metres in length was exposed at some height from the ground, and was kept charged to a high potential by connecting it to the negative terminal of an influence machine. After exposure for some hours, this wire was removed and placed inside the dissipation vessel. The rate of discharge was found to be increased many times by the presence of the wire. No increase was observed when the wire was charged positively instead of negatively. The results also showed that the radio-active matter could be removed from the wire in the same way as from a wire made active by exposure in the presence of the thorium emanation. A piece of leather moistened with ammonia was rubbed over the active wire. On testing the leather, it was found to be strongly radio-active. When a long wire was used, the amount of activity obtained on the leather was comparable with that possessed by a gram of uranium oxide.
The activity produced on the wire was not permanent, but disappeared to a large extent in the course of a few hours. The amount of activity produced on a wire of given size, exposed under similar conditions, was independent of the material of the wire. Lead, iron and copper wires gave about equal effects.
The amount of activity obtained was greatly increased by exposing a negatively charged wire in a mass of air which had been undisturbed for a long time. Experiments were made in the great cave of Wolfenbüttel, and a very large amount of activity was observed. By transferring the activity to a piece of leather it was found that the rays could appreciably light up a screen of barium platinocyanide in the dark4. The rays also darkened a photographic plate through a piece of aluminium 0·1 mm. in thickness.