1. Introduction. The close of the old and the beginning of the new century have been marked by a very rapid increase of our knowledge of that most important but comparatively little known subject—the connection between electricity and matter. No study has been more fruitful in surprises to the investigator, both from the remarkable nature of the phenomena exhibited and from the laws controlling them. The more the subject is examined, the more complex must we suppose the constitution of matter in order to explain the remarkable effects observed. While the experimental results have led to the view that the constitution of the atom itself is very complex, at the same time they have confirmed the old theory of the discontinuous or atomic structure of matter. The study of the radio-active substances and of the discharge of electricity through gases has supplied very strong experimental evidence in support of the fundamental ideas of the existing atomic theory. It has also indicated that the atom itself is not the smallest unit of matter, but is a complicated structure made up of a number of smaller bodies.
A great impetus to the study of this subject was initially given by the experiments of Lenard on the cathode rays, and by Röntgen’s discovery of the X rays. An examination of the conductivity imparted to a gas by the X rays led to a clear view of the mechanism of the transport of electricity through gases by means of charged ions. This ionization theory of gases has been shown to afford a satisfactory explanation not only of the passage of electricity through flames and vapours, but also of the complicated phenomena observed when a discharge of electricity passes through a vacuum tube. At the same time, a further study of the cathode rays showed that they consisted of a stream of material particles, projected with great velocity, and possessing an apparent mass small compared with that of the hydrogen atom. The connection between the cathode and Röntgen rays and the nature of the latter were also elucidated. Much of this admirable experimental work on the nature of the electric discharge has been done by Professor J. J. Thomson and his students in the Cavendish Laboratory, Cambridge.
An examination of natural substances, in order to see if they gave out dark radiations similar to X rays, led to the discovery of the radio-active bodies which possess the property of spontaneously emitting radiations, invisible to the eye, but readily detected by their action on photographic plates and their power of discharging electrified bodies. A detailed study of the radio-active bodies has revealed many new and surprising phenomena which have thrown much light, not only on the nature of the radiations themselves, but also on the processes occurring in those substances. Notwithstanding the complex nature of the phenomena, the knowledge of the subject has advanced with great rapidity, and a large amount of experimental data has now been accumulated.
In order to explain the phenomena of radio-activity, Rutherford and Soddy have advanced a theory which regards the atoms of the radio-active elements as suffering spontaneous disintegration, and giving rise to a series of radio-active substances which differ in chemical properties from the parent elements. The radiations accompany the breaking-up of the atoms, and afford a comparative measure of the rate at which the disintegration takes place. This theory is found to account in a satisfactory way for all the known facts of radio-activity, and welds a mass of disconnected facts into one homogeneous whole. On this view, the continuous emission of energy from the active bodies is derived from the internal energy inherent in the atom, and does not in any way contradict the law of the conservation of energy. At the same time, however, it