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nydus/The Theory of Heat RadiationPublic
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Page 146 of 236
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128.

Let us then take N similar monatomic gas molecules in an arbitrarily given thermodynamic state and try to find the corresponding entropy. The state space is six-dimensional, with the three coordinates x, y, z, and the three corresponding moments mξ, mη, mζ, of a molecule, where we denote the mass by m and velocity components by ξ, η, ζ. Hence these quantities are to be substituted for the ϕ and ψ in [sect:126.] Sec. 126. We thus obtain for the size of a region element G the sextuple integral G=m3dσ,\Label[eqn](176)\upshape (176) where, for brevity dxdydzdξdηdζ=dσ.\Label[eqn](177)\upshape (177)

If the region elements are known, then, since the macroscopic state of the system of molecules was assumed as known, the numbers N1, N2, N3,  of the molecules which lie in the separate region elements are also known, and hence the distribution densities w1, w2, w3,  [eqn:(166)] (166) are given and the entropy of the state follows at once from [eqn:(173)] (173).

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