bodies of water. Here they became mingled with various other salts, and all were precipitated out as the waters of the basins evaporated. Deliquescence and later migration of the more soluble nitrates resulted in their accumulation around the edges of the basins. The nitrate beds are thus essentially a product of desiccation.
While the origin just set forth is rather generally accepted, several other theories have been advanced. It has been suggested that the deposits were not formed in water basins, but that ground water carrying nitrates in solution has been and is rising to the surface,—where, under the extremely arid conditions, it evaporates rapidly, leaving the nitrates mixed with the surface clays. One group of writers accounts for the deposits by the fixation of atmospheric nitrogen through electrical phenomena. Still others note the frequent presence of nitrogen in volcanic exhalations and the association of the Chilean nitrate beds with surface volcanic rocks; they suggest that these rocks were the source of the nitrogen, which under unusual climatic conditions was leached out and then deposited by evaporation.
PHOSPHATES
Economic Features
The principal use of natural phosphates is in the manufacture of fertilizers. They are also used in the manufacture of phosphorus, phosphoric acid, and other phosphorus compounds, for matches, for certain metallurgical operations, and for gases used in military operations.
The material mined is mainly a phosphate of lime (tricalcium phosphate). To make it available for plant use, it is treated with sulphuric acid to form a soluble superphosphate; hence the importance of sulphuric acid, and its mineral sources pyrite and sulphur, in the fertilizer industry. A small percentage of the phosphate is also ground up and applied directly to the soil in the raw form. Other phosphatic materials are the basic slag from phosphatic iron ores made into Thomas-process steel, guano from the Pacific islands, and bone and refuse (tankage) from the cattle raising and packing countries. These materials are used for the same purposes as the natural phosphates.
The United States is the largest factor in the world's phosphate industry, with reference both to production and reserves.
The largest and most available of the European sources are in Tunis and Algeria, under French control, and in Egypt, under English control. Belgium and northern France have been considerable producers of phosphates, but, with the development of higher grade deposits in other countries, their production has fallen to a very small fraction of the world's total. There also has been very small and insignificant production in Spain and Great Britain. Russia has large reserves which are practically unmined.
While there is comparatively little phosphate rock in western Europe, a considerable amount of the phosphate supply is obtained as a by-product from Thomas slag, derived from phosphatic iron ores. These ores are chiefly from Lorraine and Sweden, but English and Russian ores can be similarly used.
Outside of Europe and the United States, there are smaller phosphate supplies in Canada, the Dutch West Indies, Venezuela, Chile, South Australia, New Zealand, and several islands of the Indian and South Pacific Oceans. None of these has yet contributed largely to world production, and their distance from the principal