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nydus/The Principles of Chemistry, Volume IPublic
Page 107 of 822
Table of Contents

CHAPTER IV OZONE AND HYDROGEN PEROXIDE—DALTON'S LAW

as redistributions of the relative positions of atoms and changes in their motion. The atomic representation of matter arose in very ancient times,37 and up to recent times was at variance with the dynamical hypothesis, which considers matter as only a manifestation of forces. At the present time, however, the majority of scientific men uphold the atomic hypothesis, although the present conception of an atom is quite different from that of the ancient philosophers. An atom at the present day is regarded rather as an individual or unit which is indivisible by physical38 and chemical forces, whilst the atom of the ancients was actually mechanically and geometrically indivisible. When Dalton (1804) discovered the law of multiple proportions, he pronounced himself in favour of the atomic doctrine, because it enables this law to be very easily understood. If the divisibility of every element has a limit, namely the atom, then the atoms of elements are the extreme limits of all divisibility, and if they differ from each other in their nature, the formation of a compound from elementary matter must consist in the aggregation of several different atoms into one whole or system of atoms, now termed particles or molecules. As atoms can only combine in their entire masses, it is evident that not only the law of definite composition, but also that of multiple proportions, must apply to the combination of atoms with one another; for one atom of a substance can combine with one, two, or three atoms of another substance, or in general one, two, three atoms of one substance are able to combine with one, two, or three atoms of another; this being the essence of the law of multiple proportions. Chemical and physical data are very well explained by the aid of the atomic theory. The displacement of one element by another follows the law of equivalency. In this case one or several atoms of a given element take the place of one or several atoms of another element in its compounds. The atoms of different substances can be mixed together in the same sense as sand can be mixed with clay. They do not unite into one whole—i.e. there is not a perfect blending in the one or other case, but only a juxtaposition, a homogeneous whole being formed from individual parts. This is the first and most simple method of applying the atomic theory to the explanation of chemical phenomena.39

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