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nydus/The Principles of Chemistry, Volume IPublic
Page 82 of 822
Table of Contents

CHAPTER III OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

by a brighter yellow flame. Metallic magnesium, which burns brightly in air, continues to burn with still greater vigour in oxygen, forming a white powder, which is a compound of magnesium with oxygen (magnesium oxide; magnesia). A strip of iron or steel does not burn in air, but an iron wire or steel spring may be easily burnt in oxygen.28 The combustion of steel or iron in oxygen is not accompanied by a flame, but sparks of oxide fly in all directions from the burning portions of the iron.29

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Fig. 30.—Mode of burning a steel spring in oxygen.

In order to demonstrate by experiment the combustion of hydrogen in oxygen, a gas-conducting tube, bent so as to form a convenient jet, is led from the vessel evolving hydrogen. The hydrogen is first set light to in air, and then the gas-conducting tube is let down into a flask containing oxygen. The combustion in oxygen will be similar to that in air; the flame remains pale, notwithstanding the fact that its temperature rises considerably. It is instructive to remark that oxygen may burn in hydrogen, just as hydrogen in oxygen. In order to show the combustion of oxygen in hydrogen, a tube bent vertically upwards and ending in a fine orifice is attached to the stopcock of a gas-holder full of oxygen. Two wires, placed at such a distance from each other as to allow the passage of a constant series of sparks from a Ruhmkorff's coil, are fixed in front of the orifice of the tube. This is in order to ignite the oxygen, which may also be done by attaching tinder round the orifice, and burning it. When the wires are arranged at the orifice of the tube, and a series of sparks passes between them, then an inverted (because of the lightness of the hydrogen) jar full of hydrogen is placed over the gas-conducting tube. When the jar covers the orifice of the gas-conducting tube (and not before, as otherwise an explosion might take place) the cock of the gasometer is opened, and the oxygen flows into the hydrogen and is set light to by the sparks. The flame obtained is similar to that formed by the combustion of hydrogen in oxygen.30 From this it is evident that the flame is the locality where the oxygen combines with the hydrogen, therefore a flame of burning oxygen can be obtained as well as a flame of burning hydrogen.

If, instead of hydrogen, any other combustible gas be taken—for example, ordinary coal gas—then the phenomenon of combustion will be exactly the same, only a bright flame will be obtained, and the products of combustion will be different. However, as coal gas contains a considerable amount of free and combined hydrogen, it will also form a considerable quantity of water in its combustion.

If hydrogen be mixed with oxygen in the proportion in which they form water—i.e. if two volumes of hydrogen be taken for each volume of oxygen—then the mixture will be the same as that obtained by the decomposition of water by a galvanic current—detonating gas.

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