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nydus/The Principles of Chemistry, Volume IPublic
Page 89 of 822
Table of Contents

CHAPTER III OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

not apparent to our senses owing to the small rise in temperature which takes place; this is owing to the slow rate of the reaction and to the transmission of the heat formed as radiant heat, &c. Thus, in the oxidation of wine and its transformation into vinegar by the usual method of preparation of the latter, the heat evolved cannot be observed because it extends over several weeks, but in the so-called rapid process of the manufacture of vinegar, when a large quantity of wine is comparatively rapidly oxidised, the evolution of heat is quite apparent.

Such slow processes of oxidation are always taking place in nature by the action of the atmosphere. Dead organisms and the substances obtained from them—such as bodies of animals, wood, wool, grass, &c.—are especially subject to this action. They rot and decompose—that is, their solid matter is transformed into gases, under the influence of moisture and atmospheric oxygen, and generally under the influence of other organisms, such as moulds, worms, micro-organisms (bacteria), and the like. These are processes of slow combustion, of slow combination with oxygen. It is well known that manure rots and develops heat, that stacks of damp hay, damp flour, straw, &c., become heated and are changed in the process.50 In all these transformations the same chief products of combustion are formed as those which are contained in smoke; the carbon gives carbonic anhydride, and the hydrogen water. Hence these processes require oxygen just like combustion. This is the reason why the entire prevention of access of air hinders these transformations,51 and an increased supply of air accelerates them. The mechanical treatment of arable lands by the plough, harrow, and other similar means has not only the object of facilitating the spread of roots in the ground, and of making the soil more permeable to water, but it also serves to facilitate the access of the air to the component parts of the soil; as a consequence of which the organic remains of soil rot—so to speak, breathe air and evolve carbonic anhydride. One acre of good garden land in the course of a summer evolves more than sixteen tons of carbonic anhydride.

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