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nydus/The Principles of Chemistry, Volume IPublic
Page 21 of 822
Table of Contents

PRINCIPLES OF CHEMISTRY INTRODUCTION

see caption
Fig. 3.—Lavoisier's apparatus for determining the composition of air and the reason of metals increasing in weight when they are calcined in air.

Lavoisier proved by means of the balance that every case of rusting of metals or oxidation, or of combustion, is accompanied by an increase in weight at the expense of the atmosphere. He formed, therefore, the natural opinion that the heavier substance is more complex than the lighter one.26 Lavoisier's celebrated experiment, made in 1774, gave indubitable support to his opinion, which in many respects was contradictory to Stahl's doctrine. Lavoisier poured four ounces of pure mercury into a glass retort (fig. 3), whose neck was bent as shown in the drawing and dipped into the vessel R S, also full of mercury. The projecting end of the neck was covered with a glass bell-jar P. The weight of all the mercury taken, and the volume of air remaining in the apparatus, namely, that in the upper portion of the retort, and under the bell-jar, were determined before beginning the experiment. It was most important in this experiment to know the volume of air in order to learn what part it played in the oxidation of the mercury, because, according to Stahl, phlogiston is emitted into the air, whilst, according to Lavoisier, the mercury in oxidising absorbs a portion of the air; and consequently it was absolutely necessary to determine whether the amount of air increased or decreased in the oxidation of the metal. It was, therefore, most important to measure the volume of the air in the apparatus both before and after the experiment. For this purpose it was necessary to know the total capacity of the retort, the volume of the mercury poured into it, the volume of the bell-jar above the level of the mercury, and also the temperature and pressure of the air at the time of its measurement. The volume of air contained in the apparatus and isolated from the surrounding atmosphere could be determined from these data. Having arranged his apparatus in this manner, Lavoisier heated the retort holding the mercury for a period of twelve days at a temperature near the boiling point of mercury. The mercury became covered with a quantity of small red scales; that is, it was oxidised or converted into an earth. This substance is the same mercury oxide which has already been mentioned (example 3). After the lapse of twelve days the apparatus was cooled, and it was then seen that the volume of the air in the apparatus had diminished during the time of the experiment. This result was in exact contradiction to Stahl's hypothesis. Out of 50 cubic inches of air originally taken, there only remained 42. Lavoisier's experiment led to other equally important results. The

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