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nydus/The Principles of Chemistry, Volume IPublic
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CHAPTER XII SODIUM

reference to many other agents. Thus carbonic anhydride combines directly with the oxide Na 2 O, which when heated in the gas burns, forming sodium carbonate, whilst the peroxide yields oxygen in addition. When treated with acids, sodium and all its oxides only form the salts corresponding with sodium oxide—that is, of the formula or type NaX. Thus the oxide of sodium, Na 2 O, is the only salt-forming oxide of this metal, as water is in the case of hydrogen. Although the peroxide H 2 O 2 is derived from hydrogen, and Na 2 O 2 from sodium, yet there are no corresponding salts known, and if they are formed they are probably as unstable as hydrogen peroxide. Although carbon forms carbonic oxide, CO, still it has only one salt-forming oxide—carbonic anhydride, CO 2 . Nitrogen and chlorine both give several salt-forming oxides and types of salts. But of the oxides of nitrogen, NO and NO 2 do not form salts, as do N 2 O 3 , N 2 O 4 , and N 2 O 5 , although N 2 O 4 does not form special salts, and N 2 O 5 corresponds with the highest form of the saline compounds of nitrogen. Such distinctions between the elements, according to their power of giving one or several saline forms, is a radical property of no less importance than the basic or acid properties of their oxides. Sodium as a typical metal does not form any acid oxides, whilst chlorine, as a typical non-metal, does not form bases with oxygen. Therefore sodium as an element may be thus characterised: it forms one very stable salt-forming oxide, Na 2 O, having powerful basic properties, and its salts are of the general formula, NaX, therefore in its compounds it is, like hydrogen, a basic and univalent element.

On comparing sodium and its analogues, which will be described later with other metallic elements, it will be seen that these properties, together with the relative lightness of the metal itself and its compounds, and the magnitude of its atomic weight comprise the most essential properties of this element, clearly distinguishing it from others, and enabling us easily to recognise its analogues.

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