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nydus/The Principles of Chemistry, Volume IPublic
Page 94 of 822
Table of Contents

CHAPTER III OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

proportion. The water here taken for solution plays no other part than merely facilitating the progress of the reaction. This is seen from the fact that the anhydrides of the acids are able to combine with basic oxides, and give the same salts as do the acids with the alkalis or hydrates. Hence, a salt is a compound of definite quantities of an acid with an alkali. In the latter reaction, water is separated out if the substance formed be the same as is produced by the combination of anhydrous oxides together.54 Examples of the formation of salts from acids and bases are easily observed, and are very often applied in practice. If we take, for instance, insoluble magnesium oxide (magnesia) it is easily dissolved in sulphuric acid, and on evaporation gives a saline substance, bitter, like all the salts of magnesium, and familiar to all under the name of Epsom salts, used as a purgative. If a solution of caustic soda—which is obtained, as we saw, by the action of water on sodium oxide—be poured into a flask in which charcoal has been burnt; or if carbonic anhydride, which is produced under so many circumstances, be passed through a solution of caustic soda, then sodium carbonate or soda, Na2CO3, is obtained, of which we have spoken several times, and which is prepared on a large scale and often used in manufactures. This reaction is expressed by the equation, 2NaHO + CO2 = Na2CO3 + H2O. Thus, the various bases and acids form an innumerable number of different salts.55 Salts constitute an example of definite chemical compounds, and both in the history and practice of science are most often cited as confirming the conception of definite chemical compounds. Indeed, all the indications of a definite chemical combination are clearly seen in the formation and properties of salts. Thus, they are produced with a definite proportion of oxides, heat is evolved in their formation,56 and the chemical character of the oxides and many of the physical properties become hidden in their salts. For example, when gaseous carbonic anhydride combines with a base to form a solid salt, the elasticity of the gas quite disappears in its passage into the salt.57

Judging from the above, a salt is a compound of basic and acid oxides, or the result of the action of hydrates of these classes on each other with separation of water. But salts may be obtained by other

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