Among the phenomena accompanying the combustion of certain substances, the phenomenon of flame attracts attention. Sulphur, phosphorus, sodium, magnesium, naphthalene, &c., burn like hydrogen with a flame, whilst in the combustion of other substances no flame is observed, as, for instance, in the combustion of iron and of charcoal. The appearance of flame depends on the capacity of the combustible substance to yield gases or vapours at the temperature of combustion. At the temperature of combustion, sulphur, phosphorus, sodium, and naphthalene pass into vapour, whilst wood, alcohol, oil, &c., are decomposed into gaseous and vaporous substances. The combustion of gases and vapours forms flames, and therefore a flame is composed of the hot and incandescent gases and vapours produced by combustion. It may easily be proved that the flames of such non-volatile substances as wood contain volatile and combustible substances formed from them, by placing a tube in the flame connected with an aspirator. Besides the products of combustion, combustible gases and liquids, previously in the flame as vapours, collect in the aspirator. For this experiment to succeed—i.e. in order to really extract combustible gases and vapours from the flame it is necessary that the suction tube should be placed inside the flame. The combustible gases and vapours can only remain unburnt inside the flame, for at the surface of the flame they come into contact with the oxygen of the air and burn.45 Flames are of different degrees of brilliancy, according to whether solid incandescent particles occur in the combustible gas or vapour, or not. Incandescent gases and vapours emit but little light by themselves, and therefore give a paler flame.46 If a flame does not contain solid particles it is transparent, pale, and emits but little light.47 The flames of burning alcohol, sulphur, and hydrogen are of this kind. A pale flame may be rendered luminous by placing fine particles of solid matter in it. Thus, if a very fine platinum wire be placed in the pale flame of burning alcohol—or, better still, of hydrogen—the flame emits a bright light. This is still better seen by sifting the powder of an incombustible substance, such as fine sand, into the flame, or by placing a bunch of asbestos threads in it. Every brilliant flame always contains some kind of solid particles, or at least some very dense vapour. The flame of sodium burning in oxygen has a brilliant yellow colour, from the presence of particles of solid sodium oxide. The flame of magnesium is brilliant from the fact that in burning it forms solid magnesia, which becomes white hot, and similarly the brilliancy of the Drummond light is due to the heat of the flame raising the solid non-volatile lime to a state of incandescence. The flames of a candle,
Table of Contents
CHAPTER III OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS
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