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nydus/The Principles of Chemistry, Volume IPublic
Page 132 of 822
Table of Contents

CHAPTER VI TTHE COMPOUNDS OF NITROGEN WITH HYDROGEN AND OXYGEN

see caption
Fig. 48.—The method of decomposition of nitrous anhydride, also applicable to the other oxides of nitrogen, and to their analysis. NO 2 is generated from nitrate of lead in the retort A. Nitric acid and other less volatile products are condensed in B. The tube C C contains copper, and is heated from below. Undecomposed volatile products (if any are formed) are condensed in D, which is cooled. If the decomposition be incomplete, brown fumes make their appearance in this receiver. The gaseous nitrogen is collected in the cylinder E.

If the vapour of nitric acid is passed through an even moderately heated glass tube, the formation of dark-brown fumes of the lower oxides of nitrogen and the separation of free oxygen may be observed, 2NHO 3 = H 2 O + 2NO 2 + O. The decomposition is complete at a white heat—that is, nitrogen is formed, 2NHO 3 = H 2 O + N 2 + O 5 . Hence it is easily understood that nitric acid may part with its oxygen to a number of substances capable of being oxidised. It is consequently an oxidising agent . Charcoal, as we have already seen, burns in nitric acid; phosphorus, sulphur, iodine, and the majority of metals also decompose nitric acid, some on heating and others even at the ordinary temperature: the substances taken are oxidised and the nitric acid is deoxidised, yielding compounds containing less oxygen. Only a few metals, such as gold and platinum, do not act on nitric acid, but the majority decompose it; in so doing, an oxide of the metal is formed, which, if it has the character of a base, acts on the remaining nitric acid; hence, with the majority of metals the result of the reaction is usually not an oxide of the metal, but the corresponding salt of nitric acid, and, at the same time, one of the lower oxides of nitrogen. The resulting salts of the metals are soluble, and hence it is said that nitric acid dissolves nearly all metals. This

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