into the composition of nearly all rocks, contain lime and magnesia and silica. The majority of the primary rocks also contain alumina, potash, and soda. These rocks, under the action of water (containing carbonic acid) and air, give up lime and magnesia to the water, and therefore they are contained in all kinds of water, and especially in sea-water. The carbonates CaCO 3 and MgCO 3 , frequently met with in nature, are soluble in an excess of water saturated with carbonic anhydride , and therefore many natural waters contain these salts, and are able to yield them when evaporated. However, one kilogram of water saturated with carbonic anhydride does not dissolve more than three grams of calcium carbonate. By gradually expelling the carbonic anhydride from such water, an insoluble precipitate of calcium carbonate separates out. It may confidently be stated that the formation of the very widely distributed strata of calcium and magnesium carbonates was of this nature, because these strata are of a sedimentary character—that is, such as would be exhibited by a gradually accumulating deposit on the bottom of the sea, and, moreover, frequently containing the remains of marine plants, and animals, shells, &c. It is very probable that the presence of these organisms in the sea has played the chief part in the precipitation of the carbonates from the sea water, because the plants absorb CO 2 , and many of the organisms CaCO 3 , and after death give deposits of carbonate of lime; for instance, chalk, which is almost entirely composed of the minute remains of the calcareous shields of such organisms. These deposits of calcium and magnesium carbonates are the most important sources of these metals. Lime generally predominates, because it is present in rocks and running water in greater quantity than magnesia, and in this case these sedimentary rocks are termed limestone . Some common flagstones used for paving, &c., and chalk may be taken as examples of this kind of formation. Those limestones in which a considerable portion of the calcium is replaced by magnesium are termed dolomites . The dolomites are distinguished by their hardness, and by their not parting with the whole of their carbonic anhydride so easily as the limestones under the action of acids. Dolomites sometimes contain an equal number of molecules of calcium carbonate and magnesium carbonate, and they also sometimes appear in a crystalline form, which is easily intelligible, because calcium carbonate itself is exceedingly common in this form in nature, and is then known as calc spar , whilst natural crystalline magnesium carbonate is termed magnesite . The formation of the crystalline varieties of the insoluble carbonates is explained by the possibility of a slow deposition from solutions containing carbonic acid. Besides which (Chapter
Table of Contents
CHAPTER XIV THE VALENCY AND SPECIFIC HEAT OF THE METALS. MAGNESIUM. CALCIUM, STRONTIUM, BARIUM, AND BERYLLIUM
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