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nydus/The Principles of Chemistry, Volume IPublic
Page 22 of 822
Table of Contents

PRINCIPLES OF CHEMISTRY INTRODUCTION

weight of the air taken decreased by as much as the weight of the mercury increased in oxidising; that is, the portion of the air was not destroyed, but only combined with mercury. This portion of the air may be again separated from the mercury oxide and has, as we saw (example 3), properties different from those of air. It is called ‘oxygen.’ That portion of the air which remained in the apparatus and did not combine with the mercury does not oxidise metals, and cannot support either combustion or respiration, so that a lighted taper is immediately extinguished if it be dipped into the gas which remains in the bell-jar. ‘It is extinguished in the residual gas as if it had been plunged into water,’ writes Lavoisier in his memoirs. This gas is called ‘nitrogen.’ Thus air is not a simple substance, but consists of two gases, oxygen and nitrogen, and therefore the opinion that air is an elementary substance is erroneous. The oxygen of the air is absorbed in combustion and the oxidation of metals, and the earths produced by the oxidation of metals are substances composed of oxygen and a metal. By mixing the oxygen with the nitrogen the same air as was originally taken is re-formed. It has also been shown by direct experiment that on reducing an oxide with carbon, the oxygen contained in the oxide is transferred to the carbon, and gives the same gas that is obtained by the combustion of carbon in air. Therefore this gas is a compound of carbon and oxygen, just as the earthy oxides are composed of metals and oxygen.

The many examples of the formation and decomposition of substances which are met with convince us that the majority of substances with which we have to deal are compounds made up of several other substances. By heating chalk (or else copper carbonate, as in the second example) we obtain lime and the same carbonic acid gas which is produced by the combustion of carbon. On bringing lime into contact with this gas and water, at the ordinary temperature, we again obtain the compound, carbonate of lime, or chalk. Therefore chalk is a compound. So also are those substances from which it may be built up. Carbonic anhydride is formed by the combination of carbon and oxygen; and lime is produced by the oxidation of a certain metal called ‘calcium.’ By resolving substances in this manner into their component parts, we arrive at last at such as are indivisible into two or more substances by any means whatever, and which cannot be formed from other substances. All we can do is to make such substances combine together to act on other substances. Substances which cannot be formed from or decomposed into others are termed simple substances (elements). Thus all homogeneous substances may be classified into simple and compound substances. This view was introduced and established as a scientific fact during the lifetime of Lavoisier. The number of these elements is very small in comparison with the number of compound substances which are formed by them. At the present time, only seventy elements are known with certainty to exist. Some of them are very rarely met with in nature, or are found in very small quantities, whilst the existence of others is still doubtful. The number of elements with whose compounds we commonly deal in everyday life is very small. Elements cannot be transmuted into one another—at least up to the present not a single case of such a transformation has been met with; it may therefore be said that, as yet, it is impossible to transmute one metal into another. And as yet, notwithstanding the number of attempts which have been made in this direction, no fact has been discovered which could in any way support the idea of the complexity of such well-known elements27 as oxygen, iron, sulphur, &c. Therefore, from its very conception, an element is not susceptible to reactions of decomposition.28

The quantity, therefore, of each element remains constant in all chemical changes: a fact which may be deduced as a consequence of the law of the indestructibility of matter, and of the conception of elements themselves. Thus the equation expressing the law of the indestructibility of matter acquires a new and still more important signification. If we know the quantities of the elements which occur in the re-acting substances, and if from these substances there proceed, by means of chemical changes, a series of new

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