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nydus/The Principles of Chemistry, Volume IPublic
Page 41 of 822
Table of Contents

CHAPTER I ON WATER AND ITS COMPOUNDS

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Fig. 14.—Method of transferring a gas into a cylinder filled with mercury and whose open end is immersed under the mercury in a bath having two glass sides. The apparatus containing the gas is represented on the right. Its upper extremity is furnished with a tube extending under the cylinder. The lower part of the vessel communicates with a vertical tube. If mercury be poured into this tube, the pressure of the gas in the apparatus is increased, and it passes through the gas-conducting tube into the cylinder, where it displaces the mercury, and can be measured or subjected to the action of absorbing agents, such as water.

It is well known that water dissolves many substances. Salt, sugar, alcohol, and a number of other substances, dissolve in water and form homogeneous liquids with it. To demonstrate the solubility of gases in water, a gas should be taken which has a high co-efficient of solubility—for instance, ammonia. This is introduced into a bell jar (or cylinder, as in fig. 14), which is previously filled with mercury and stands in a mercury bath. If water be then introduced into the cylinder, the mercury will rise, owing to the water dissolving the ammonia gas. If the column of mercury be less than the barometric column, and if there be sufficient water to dissolve the gas, all the ammonia will be absorbed by the water. The water is introduced into the cylinder by a glass pipette, with a bent end. The bent end is put into water, and the air is sucked out from the upper end. When full of water, its upper end is closed with the finger, and the bent end placed in the mercury bath under the orifice of the cylinder. On blowing into the pipette the water will rise to the surface of the mercury in the cylinder owing to its lightness. The solubility of a gas like ammonia may be demonstrated by taking a flask full of the gas, and closed by a cork with a tube passing through it. On placing the tube under water, the water will rise into the flask (this may be accelerated by previously warming the flask), and begin to play like a fountain inside it. Both the rising of the mercury and the fountain clearly show the considerable affinity of water for ammonia gas, and the force acting in this dissolution is rendered evident. A certain period of time is

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