A wide porcelain tube P (fig. 19) is placed in a furnace, which can be raised to a high temperature (it should be heated with small pieces of good coke). In this tube there is inserted a second tube T, of smaller diameter, made of unglazed earthenware and therefore porous. The ends of the tube are luted to the wide tube, and two tubes, C and C', are inserted into the ends, as shown in the drawing. With this arrangement it is possible for a gas to pass into the annular space between the walls of the two tubes, from whence it can be collected. Steam from a retort or flask is passed through the tube D, into the inner porous tube T. This steam on entering the red-hot space is decomposed into hydrogen and oxygen. The densities of these gases are very different, hydrogen being sixteen times lighter than oxygen. Light gases, as we saw above, penetrate through porous surfaces very much more rapidly than denser gases, and therefore the hydrogen passes through the pores of the tube into the annular space very much more rapidly than the oxygen. The hydrogen which separates out into the annular space can only be collected when this space does not contain any oxygen. If any air remains in this space, then the hydrogen which separates out will combine with its oxygen and form water. For this reason a gas incapable of supporting combustion—for instance, nitrogen or carbonic anhydride—is previously passed into the annular space. Thus the carbonic anhydride is passed through the tube C, and the hydrogen, separated from the steam, is collected through the tube C', and will be partly mixed with carbonic anhydride. A certain portion of the carbonic anhydride will penetrate through the pores of the unglazed tube into the interior of the tube T. The oxygen will remain in this tube, and the volume of the remaining oxygen will be half that of the volume of hydrogen which separates out from the annular space.8
The decomposition of water is effected much more easily by a method of substitution, taking advantage of the affinity of substances for the oxygen or the hydrogen of water. If a substance be added to water, which takes up the oxygen and replaces the hydrogen—then we shall obtain the latter gas from the water. Thus with sodium, water gives hydrogen, and with chlorine, which takes up the hydrogen, oxygen is obtained.