be artificially produced by slow crystallisation at the ordinary temperature, it appears in the rhombohedral form, but if the crystallisation be aided by heat it then appears as aragonite. It may therefore be supposed that calc spar presents the form corresponding with a low temperature, and aragonite with a higher temperature during crystallisation.
Calcium sulphate in combination with two equivalents of water, CaSO4,2H2O, is very widely distributed in nature, and is known as gypsum. Gypsum loses one and a half and two equivalents of water at a moderate temperature,49 and anhydrous or burnt gypsum is then obtained, which is also known as plaster of Paris, and is employed in large quantities for modelling.50 This use depends on the fact that burnt and finely-divided and sifted gypsum forms a paste when mixed with water; after a certain time this paste becomes slightly heated and solidifies, owing to the fact that the anhydrous calcium sulphate, CaSO4, again combines with water. When the plaster of Paris and water are first made into a paste they form a mechanical mixture, but when the mass solidifies, then a compound of the calcium sulphate with two molecules of water is produced; and this may be regarded as derived from S(OH)6 by the substitution of two atoms of hydrogen by one atom of bivalent calcium. Natural gypsum sometimes appears as perfectly colourless, or variegated, marble-like, masses, and sometimes in perfectly colourless crystals, selenite, of specific gravity 2·33. The semi-transparent gypsum, or alabaster, is often carved into small statues. Besides which an anhydrous calcium sulphate, CaSO4, called anhydrite (specific gravity 2·97), occurs in nature. It sometimes occurs along with gypsum. It is no longer capable of combining directly with water, and differs in this respect from the anhydrous salt obtained by gently igniting gypsum. If gypsum be very strongly heated it shrinks and loses its power of combining with water.51 One part of calcium sulphate requires at 0° 525 parts of water for solution, at 38° 466 parts, and at 100° 571 parts of water. The maximum solubility of gypsum is at about 36°, which is nearly the same temperature as that at which sodium sulphate is most soluble.52
As lime is a more energetic base than magnesia, so calcium chloride, CaCl2, is not so easily decomposed by water, and its solutions only disengage a small quantity of hydrochloric acid when evaporated, and when the evaporation is conducted in a stream of hydrochloric acid it easily gives an anhydrous salt which fuses at 719°; otherwise an aqueous solution yields a crystallo-hydrate, CaCl2,6H2O, which melts at 30°.53
Just as for potassium, K = 39 (and sodium, Na = 23), there