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nydus/The Principles of Chemistry, Volume IPublic
Page 259 of 822
Table of Contents

CHAPTER XIII POTASSIUM, RUBIDIUM, CÆSIUM, AND LITHIUM. SPECTRUM ANALYSIS

Potassium is quite as volatile as sodium, if not more so. At the ordinary temperature potassium is even softer than sodium; its freshly-cut surfaces present a whiter colour than sodium, but, like the latter, and with even greater ease, it oxidises in moist air. It is brittle at low temperatures, but is quite soft at 25°, and melts at 58°. At a low red heat (667°, Perkin) it distils without change, forming a green vapour, whose density,23 according to A. Scott (1887), is equal to 19 (if that of hydrogen = 1). This shows that the molecule of potassium (like that of sodium, mercury, and zinc) contains but one atom. This is also the case with many other metals, judging by recent researches.24 The specific gravity of potassium at 15° is 0·87, and is therefore less than that of sodium, as is also the case with all its compounds.25 Potassium decomposes water with great ease at the ordinary temperature, evolving 45,000 heat units per atomic weight in grams. The heat evolved is sufficient to inflame the hydrogen, the flame being coloured violet from the presence of particles of potassium.26

With regard to the relation of potassium to hydrogen and oxygen, it is closely analogous to sodium in this respect. Thus, with hydrogen it forms potassium hydride, K2H (between 200° and 411°), and with oxygen it gives a suboxide K4O, oxide K2O, and peroxide, only more oxygen enters into the composition of the latter than in sodium peroxide; potassium peroxide contains KO2, but it is probable that in the combustion of potassium an oxide KO is also formed. Potassium, like sodium, is soluble in mercury.27 In a word, the relation between sodium and potassium is as close as that between chlorine and bromine, or, better still, between fluorine and chlorine, as the atomic weight of sodium, 23, is as much greater than that of fluorine, 19, as that of potassium, 39, is greater than that of chlorine, 35·5.

The resemblance between potassium and sodium is so great that their compounds can only be easily distinguished in the form of certain of their salts. For instance, the acid potassium tartrate, C 4 H 5 KO 6 (cream of tartar), is distinguished by its sparing solubility in water and in alcohol, and in a solution of tartaric acid, whilst the corresponding sodium salt is easily soluble. Therefore,

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