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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

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Table of Contents

CHAPTER XIV THE VALENCY AND SPECIFIC HEAT OF THE METALS. MAGNESIUM. CALCIUM, STRONTIUM, BARIUM, AND BERYLLIUM

the brilliancy is due to the formation of finely divided infusible calcium oxide. Judging from the fact that calcium in burning gives a very large flame, it is probable that this metal is volatile. Calcium decomposes water at the ordinary temperature, and is oxidised in moist air, but not so rapidly as sodium. In burning, it gives its oxide or lime, CaO, a substance which is familiar to every one, and of which we have already frequently had occasion to speak. This oxide is not met with in nature in a free state, because it is an energetic base which everywhere encounters acid substances forming salts with them. It is generally combined with silica, or occurs as calcium carbonate or sulphate. The carbonate and nitrate are decomposed, at a red heat, with the formation of lime. As a rule, the carbonate, which is so frequently met with in nature, serves as the source of the calcium oxide, both commercial and pure. When heated, calcium carbonate dissociates: CaCO3 = CaO + CO2. In practice the decomposition is conducted at a bright red heat, in the presence of steam, or a current of a foreign gas, in heaps or in special kilns.40

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Fig. 78.—Continually-acting kiln for burning lime. The lime is charged from above and calcined by four lateral grates, R, M. D, fire-bars. B, space for withdrawing the burnt lime. K, stoke-house. M. fire grate. Q, R, under-grate.

Calcium oxide—that is, quicklime—is a substance (sp. gr. 3·15) which is unaffected by heat, and may therefore serve as a fire-resisting material, and was employed

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