The products of the metalepsis of alkaline hydrates, NaClO and Ca(ClO) 2 , which are present in solutions of ‘Javelle salt’ and bleaching powder (they are not obtained free from metallic chlorides), must be counted as salts, because their metals are capable of substitution. But the hydrate HClO corresponding with these salts, or hypochlorous acid , is not obtained in a free or pure state, for two reasons: in the first place, because this hydrate, as a very feeble acid, splits up (like H 2 CO 3 or HNO 3 ) into water and the anhydride, or chlorine monoxide , Cl 2 O = 2HClO - H 2 O; and, in the second place, because, in a number of instances, it evolves oxygen with great facility, forming hydrochloric acid: HClO = HCl + O. Both hypochlorous acid and chlorine monoxide may be regarded as products of the metalepsis of water, because HOH corresponds with ClOH and ClOCl. Hence in many instances bleaching salts (a mixture of hypochlorites and chlorides) break up, with the evolution of (1) chlorine , under the action of an excess of a powerful acid capable of evolving hydrochloric acid from sodium or calcium chlorides, and this takes place most simply under the action of hydrochloric acid itself, because (p. 462) NaCl + NaClO + 3HCl = 2NaCl + HCl + Cl 2 + H 2 O; (2) oxygen , as we saw in Chapter III.—The bleaching properties and, in general, oxidising action of bleaching salts is based on this evolution of oxygen (or chlorine); oxygen is also disengaged on heating the dry salts—for instance,
Table of Contents
Chapter XI The Halogens: Chlorine, Bromine, Iodine, and Fluorine
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