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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

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Table of Contents

CHAPTER III OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS

are capable of combining with the bases, are termed anhydrides of the acids or acid oxides . Sulphuric anhydride, SO 3 , may be taken as a type of the latter group. It is a compound of sulphur with oxygen formed not directly but by the addition of a fresh quantity of oxygen to sulphurous anhydride, SO 2 , by passing it together with oxygen over incandescent spongy platinum. Carbonic anhydride (often termed ‘carbonic acid’), CO 2 , phosphoric anhydride, sulphurous anhydride, are all acid oxides, for they can combine with such oxides as lime or calcium oxide, magnesia or magnesium oxide, MgO, soda or sodium oxide, Na 2 O, &c.

If a given element form but one basic oxide, it is termed the oxide; for example, calcium oxide, magnesium oxide, potassium oxide. Some indifferent oxides are also called ‘oxides’ if they have not the properties of peroxides, and at the same time do not show the properties of acid anhydrides—for example, carbonic oxide, of which mention has already been made. If an element forms two basic oxides (or two indifferent oxides not having the characteristics of a peroxide) then that of the lower degree of oxidation is called a suboxide—that is, suboxides contain less oxygen than oxides. Thus, when copper is heated to redness in a furnace it increases in weight and absorbs oxygen, until for 63 parts of copper there is absorbed not more than 8 parts of oxygen by weight, forming a red mass, which is suboxide of copper; but if the roasting be prolonged, and the draught of air increased, 63 parts of copper absorb 16 parts of oxygen, and form black oxide of copper. Sometimes to distinguish between the degrees of oxidation a change of suffix is made in the oxidised element, -ic oxide denoting the higher degree of oxidation, and -ous oxide the lower degree. Thus ferrous oxide and ferric oxide are the same as suboxide of iron and oxide of iron. If an element forms one anhydride only, then it is named by an adjective formed from the name of the element made to end in -ic and the word anhydride. When an element forms two anhydrides, then the suffixes -ous and -ic are used to distinguish them: -ous signifying less oxygen than -ic; for example, sulphurous and sulphuric anhydrides.52 When several oxides are formed from the same element, the prefixes mon, di, tri, tetra are used, thus:

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