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nydus/The Principles of Chemistry, Volume IPublic
Page 40 of 868
Table of Contents

Introduction

It is very important to direct attention to the fact that the internal motion or condition of the parts of the particles of matter must be different on the surface of a substance from what it is inside; because in the interior of a substance similar particles are acting on all sides of every particle, whilst at the surface they act on one side only.

Therefore, the condition of a substance at its surfaces of contact with other substances must be more or less modified by them—it may be in a manner similar to that caused by an elevation of temperature.

These considerations throw some light on the action in the large class of contact reactions; that is, such as appear to proceed from the mere presence (contact) of certain special substances. Porous or powdery substances are very prone to act in this way, especially spongy platinum and charcoal. For example, sulphurous anhydride does not combine directly with oxygen, but this reaction takes place in the presence of spongy platinum.38

The above general and introductory chemical conceptions cannot be thoroughly grasped in their true sense without a knowledge of the particular facts of chemistry to which we shall now turn our attention.

It was, however, absolutely necessary to become acquainted on the very threshold with such fundamental principles as the laws of the indestructibility of matter and of the conservation of energy, since it is only by their acceptance, and under their direction and influence, that the examination of particular facts can give practical and fruitful results.

Footnotes:

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