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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

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Table of Contents

CHAPTER I ON WATER AND ITS COMPOUNDS

From what has been said above, it is evident that the transference of moisture to gases and the absorption of hygroscopic moisture present great resemblance to, but still are not, chemical combinations with water. Water, when combined as hygroscopic water, does not lose its properties and does not form new substances.15

The attraction of water for substances which dissolve in it is of a different character. In the solution of substances in water there proceeds a peculiar kind of indefinite combination; a new homogeneous substance is formed from the two substances taken. But here also the bond connecting the substances is very unstable. Water containing different substances in solution boils at a temperature near to its usual boiling point. From the solution of substances which are lighter than water itself, there are obtained solutions of a less density than water—as, for example, in the solution of alcohol in water; whilst a heavier substance in dissolving in water gives it a higher specific gravity. Thus salt water is heavier than fresh.16

We will consider aqueous solutions somewhat fully, because, among other reasons, solutions are constantly being formed on the earth and in the waters of the earth, in plants and in animals, in chemical processes and in the arts, and these solutions play an important part in the chemical transformations which are everywhere taking place, not only because water is everywhere met with, but chiefly because a substance in solution presents the most favourable conditions for the process of chemical changes, which require a mobility of parts and a possible distension of parts. In dissolving, a solid substance acquires a mobility of parts, and a gas loses its elasticity, and therefore reactions often take place in solutions which do not proceed in the undissolved substances. Further, a substance, distributed in water, evidently breaks up—that is, becomes more like a gas and acquires a greater mobility of parts. All these considerations require that in describing the properties of substances, particular attention should be paid to their relation to water as a solvent.

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