Codal
nydus/The Principles of Chemistry, Volume IPublic
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Table of Contents

CHAPTER XIV THE VALENCY AND SPECIFIC HEAT OF THE METALS. MAGNESIUM. CALCIUM, STRONTIUM, BARIUM, AND BERYLLIUM

the weight of two equivalents, for n -valent metals it is equal to the weight of n equivalents. Thus aluminium, Al = 27, is trivalent, that is, its equivalent = 9; magnesium, Mg = 24, is bivalent, and its equivalent = 12. Therefore, if potassium or sodium, or in general a univalent metal, M, give compounds M 2 O, MHO, MCl, MNO 3 , M 2 SO 4 , &c., and in general MX, then for bivalent metals like magnesium or calcium the corresponding compounds will be MgO, Mg(HO) 2 , MgCl 2 , Mg(NO 3 ) 2 , MgSO 4 , &c., or in general MX 2 .

By what are we to be guided in ascribing to some metals univalency and to others bi-, ter-, quadri-, ... n-valency? What obliges us to make this difference? Why are not all metals given the same valency—for instance, why is not magnesium considered as univalent?

If this be done, taking Mg = 12 (and not 24 as now), not only is a simplicity of expression of the composition of all the compounds of magnesium attained, but we also gain the advantage that their composition will be the same as those of the corresponding compounds of sodium and potassium. These combinations were so expressed formerly—why has this since been changed?

These questions could only be answered after the establishment of the idea of multiples of the atomic weights as the minimum quantities of certain elements combining with others to form compounds—in a word, since the time of the establishment of Avogadro-Gerhardt's law (Chapter VII.). By taking such an element as arsenic, which has many volatile compounds, it is easy to determine the density of these compounds, and therefore to establish their molecular weights, and hence to find the indubitable atomic weight, exactly as for oxygen, nitrogen, chlorine, carbon, &c. It appears that As = 75, and its compounds correspond, like the compounds of nitrogen, with the forms AsX 3 , and AsX 5 ;

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