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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

Page 23 of 823
Table of Contents

PRINCIPLES OF CHEMISTRY INTRODUCTION

compound substances, then the latter will together contain the same quantity of each of the elements as there originally existed in the re-acting substances. The essence of chemical change is embraced in the study of how, and with what substances, each element is combined before and after change.

In order to be able to express various chemical changes by equations, it has been agreed to represent each element by the first or some two letters of its (Latin) name. Thus, for example, oxygen is represented by the letter O; nitrogen by N; mercury (hydrargyrum) by Hg; iron (ferrum) by Fe; and so on for all the elements, as is seen in the tables on page 24. A compound substance is represented by placing the symbols representing the elements of which it is made up side by side. For example, red mercury oxide is represented by HgO, which shows that it is composed of oxygen and mercury. Besides this, the symbol of every element corresponds with a certain relative quantity of it by weight, called its ‘combining’ weight, or the weight of an atom; so that the chemical formula of a compound substance not only designates the nature of the elements of which it is composed, but also their quantitative proportion. Every chemical process may be expressed by an equation composed of the formulæ corresponding with those substances which take part in it and are produced by it. The amount by weight of the elements in every chemical equation must be equal on both sides of the equation, since no element is either formed or destroyed in a chemical change.

On pages 24, 25, and 26 a list of the elements, with their symbols and combining or atomic weights, is given, and we shall see afterwards on what basis the atomic weights of elements are determined. At present we will only point out that a compound containing the elements A and B is designated by the formula An Bm, where m and n are the coefficients or multiples in which the combining weights of the elements enter into the composition of the substance. If we represent the combining weight of the substance A by a and that of the substance B by b, then the composition of the substance An Bm will be expressed thus: it contains na parts by weight of the substance A and mb parts by weight of the substance B, and consequently 100 parts of our compound contain

na 100 / na + mb

percentage parts by weight of the substance A and

mb 100 / na + mb

of the substance B. It is evident that as a formula shows the relative amounts of all the elements contained in a compound, the actual weights of the elements contained in a given weight of a compound may be calculated from its formula. For example, the formula NaCl of table salt shows (as Na = 23 and Cl = 35·5) that 58·5 lbs. of salt contain 23 lbs. of sodium and 35·5 lbs. of chlorine, and that 100 parts of it contain 39·3 per cent. of sodium and 60·7 per cent. of chlorine.

What has been said above clearly limits the province of chemical changes, because from substances of a given kind there can be obtained only such as contain the same elements. Even with this limitation, however, the number of possible combinations is infinitely great. Only a comparatively small number of compounds have yet been described or subjected to research, and any one working in this direction may easily discover new compounds which had not before been obtained. It often happens, however, that such newly-discovered compounds were foreseen by chemistry, whose object is the apprehension of that uniformity which rules over the multitude of compound substances, and whose aim is the comprehension of those laws which govern their formation and properties. The conception of elements having been established, the next objects

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