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nydus/The Principles of Chemistry, Volume IPublic
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Table of Contents

CHAPTER X SODIUM CHLORIDE—BERTHOLLET'S LAWS—HYDROCHLORIC ACID

Generally the evaporation in the graduator is not carried beyond a concentration of 12 to 15 parts of salt in 100 parts of solution. Strong natural solutions of salt, and also the graduated solutions, are evaporated in large shallow metallic vessels, which are either heated by the direct action of the flame from below or from above. These vessels are made of boiler plate, and are called salt-pans. Various means are employed for accelerating the evaporation and for economising fuel, which are mainly based on an artificial draught to carry off the steam as it is formed, and on subjecting the saline solution to a preliminary heating by the waste heat of the steam and furnace gases. Furthermore, the first portions of the salt which crystallise out in the salt-pans are invariably contaminated with gypsum, since the waters of saline springs always contain this substance. It is only the portions of the salt which separate later that are distinguished by their great purity. The salt is ladled out as it is deposited, left to drain on inclined tables and then dried, and in this manner the so-called bay salt is obtained. Since it has become possible to discover the saline deposits themselves, the extraction of table salt from the water of saline springs by evaporation, which previously was in general use, has begun to be disused, and is only able to hold its ground in places where fuel is cheap.

In order to understand the full importance of the extraction of salt, it need only be mentioned that on the average 20 lbs. of table salt are consumed yearly per head of population, directly in food or for cattle.

In those countries where common salt is employed in technical processes, and especially in England, almost an equal quantity is consumed in the production of substances containing chlorine and sodium, and especially in the manufacture of washing soda, &c., and of chlorine compounds (bleaching powder and hydrochloric acid).

The yearly production of salt in Europe amounts to as much as 7½ million tons.

Although certain lumps of rock salt and crystals of bay salt sometimes consist of almost pure sodium chloride, still the ordinary commercial salt contains various impurities, the most common of which are magnesium salts. If the salt be pure, its solution gives no precipitate with sodium carbonate, Na 2 CO 3 , showing the absence of magnesium salts, because magnesium carbonate, MgCO 3 , is insoluble in water. Rock salt, which is ground for use, generally contains also a considerable admixture of clay and other insoluble impurities. For ordinary use the bulk of the salt obtained can be employed directly without further purification; but some salts are purified by solution and crystallisation of the solution after standing, in which case the evaporation is not carried on to dryness, and the impurities remain in the mother liquor or in the sediment. When perfectly pure salt is required for chemical purposes it is best obtained as follows: a saturated solution of table salt is prepared, and hydrochloric acid gas is passed through it; this precipitates the sodium chloride (which is not soluble in a strong solution of hydrochloric acid), while the impurities remain in solution.

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