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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

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Table of Contents

CHAPTER VII MOLECULES AND ATOMS. THE LAWS OF GAY-LUSSAC AND AVOGADRO-GERHARDT

but also the substances formed, exhibit a simple relation of volume when measured as vapour or gas.5

When a compound is formed from two or more components, there may or may not be a contraction; the volume of the reacting substances is in this case either equal to or greater than the volume of the resultant compound. The reverse is naturally observed in the case of decompositions, when from one substance there are produced several of simpler nature. Therefore in the future we shall term combination a reaction in which a contraction is observed—that is, a diminution in the volume of the component bodies in a state of vapour or gas; and we shall term decomposition a reaction in which an expansion is produced; while those reactions in which the volumes in a gaseous or vaporous state remain constant (the volumes being naturally compared at the same temperature and pressure) we shall term reactions of substitution or of double decomposition. Thus the transition of oxygen into ozone is a reaction of combination, the formation of nitrous oxide from oxygen and nitrogen will also be a combination, the formation of nitric oxide from the same will be a reaction of substitution, the action of oxygen on nitric oxide a combination, and so on.

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