Codal
nydus/The Principles of Chemistry, Volume IPublic
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Table of Contents

Introduction

give back the original substances. For example, salt dissolves in water at the ordinary temperature, and the solution so obtained is capable of breaking up at the same temperature, leaving salt and separating the water by evaporation. Carbon bisulphide is formed from sulphur and carbon at about the same temperature at which it can be resolved into sulphur and carbon. Iron, at a certain temperature, separates hydrogen from water, forming iron oxide, which, in contact with hydrogen at the same temperature, is able to produce iron and water.

It is evident that if two substances, A and B, give two others C and D, and the reaction be reversible, then C and D will form A and B, and, consequently, by taking a definite mass of A and B, or a corresponding mass of C and D, we shall obtain, in each case, all four substances—that is to say, there will be a state of chemical equilibrium between the reacting substances.

By increasing the mass of one of the substances we obtain a new condition of equilibrium, so that reversible reactions present a means of studying the influence of mass on the modus operandi of chemical changes.

Many of those reactions which occur with very complicated compounds or mixtures may serve as examples of non-reversible reactions.

Thus many of the compound substances of animal and vegetable organisms are broken up by heat, but cannot be re-formed from their products of decomposition at any temperature.

Gunpowder, as a mixture of sulphur, nitre, and carbon, on being exploded, forms gases from which the original substances cannot be re-formed at any temperature.

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