CodalSearch this book — or all of Codal…⌘K
nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

Page 121 of 823
Table of Contents

CHAPTER VI TTHE COMPOUNDS OF NITROGEN WITH HYDROGEN AND OXYGEN

see caption
Fig. 42.—The dry distillation of bones on a large scale. The bones are heated in the vertical cylinders C (about 1½ metre high and 30 centimetres in diameter). The products of distillation pass through the tubes T, into the condenser B, and receiver F. When the distillation is completed the trap H is opened, and the burnt bones are loaded into trucks V. The roof M is then opened, and the cylinders are charged with a fresh quantity of bones. The ammonia water is preserved, and goes to the preparation of ammoniacal salts, as described in the following drawing.

In the last chapter we saw that nitrogen does not directly combine with hydrogen, but that a mixture of these gases in the presence of hydrochloric acid gas, HCl, forms ammonium chloride, NH 4 Cl, on the passage of a series of electric sparks. In ammonium chloride, HCl is combined with NH 3 , consequently N with H 3 forms ammonia. Almost all the nitrogenous substances of plants and animals evolve ammonia when heated with an alkali. But even without the presence of an alkali the majority of nitrogenous substances, when decomposed or heated with a limited supply of air, evolve their nitrogen, if not entirely, at all events partially, in the form of ammonia. When animal substances such as skins, bones, flesh, hair, horns, &c., are heated without access of air in iron retorts—they undergo what is termed dry distillation. A portion of the resultant substances remains in the retort and forms a carbonaceous residue, whilst the other portion, in virtue of its volatility, escapes through the tube leading from the retort. The vapours given off, on cooling, form a liquid which separates into two layers; the one, which is oily, is composed of the so-called animal oils ( oleum animale ): the other, an aqueous layer, contains a solution of ammonia salts. If this solution be mixed with lime and heated, the lime takes up the elements of carbonic acid from the ammonia salts, and ammonia is evolved as a gas. In ancient times ammonia compounds were imported into Europe from Egypt, where they were prepared from the soot obtained in the employment of camels' dung as fuel in the locality of the temple of Jupiter Ammon (in Lybia), and therefore the salt obtained was called ‘sal-ammoniacale,’ from which the

121