In the last chapter we saw that nitrogen does not directly combine with hydrogen, but that a mixture of these gases in the presence of hydrochloric acid gas, HCl, forms ammonium chloride, NH 4 Cl, on the passage of a series of electric sparks. In ammonium chloride, HCl is combined with NH 3 , consequently N with H 3 forms ammonia. Almost all the nitrogenous substances of plants and animals evolve ammonia when heated with an alkali. But even without the presence of an alkali the majority of nitrogenous substances, when decomposed or heated with a limited supply of air, evolve their nitrogen, if not entirely, at all events partially, in the form of ammonia. When animal substances such as skins, bones, flesh, hair, horns, &c., are heated without access of air in iron retorts—they undergo what is termed dry distillation. A portion of the resultant substances remains in the retort and forms a carbonaceous residue, whilst the other portion, in virtue of its volatility, escapes through the tube leading from the retort. The vapours given off, on cooling, form a liquid which separates into two layers; the one, which is oily, is composed of the so-called animal oils ( oleum animale ): the other, an aqueous layer, contains a solution of ammonia salts. If this solution be mixed with lime and heated, the lime takes up the elements of carbonic acid from the ammonia salts, and ammonia is evolved as a gas. In ancient times ammonia compounds were imported into Europe from Egypt, where they were prepared from the soot obtained in the employment of camels' dung as fuel in the locality of the temple of Jupiter Ammon (in Lybia), and therefore the salt obtained was called ‘sal-ammoniacale,’ from which the
Table of Contents
CHAPTER VI TTHE COMPOUNDS OF NITROGEN WITH HYDROGEN AND OXYGEN
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