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nydus/The Principles of Chemistry, Volume IPublic
Page 293 of 822
Table of Contents

CHAPTER XIV THE VALENCY AND SPECIFIC HEAT OF THE METALS. MAGNESIUM. CALCIUM, STRONTIUM, BARIUM, AND BERYLLIUM

directly (Maquenne, 1892) by heating the metals in nitrogen. They all have the appearance of an amorphous powder of dark colour; as regards their reactions, it is known that besides disengaging ammonia with water, they form cyanides when heated with carbonic oxide; for instance, Ba 3 N 2 + 2CO = Ba(CN) 2 + 2BaO.

The metals of the alkaline earths, just like Na and K, absorb hydrogen under certain conditions, and form pulverulent easily oxidisable metallic hydrides, whose composition corresponds exactly to that of Na 2 H and K 2 H, with the substitution of K 2 and Na 2 by the atoms Be, Mg, Ca, Sr, and Ba. The hydrides of the metals of the alkaline earths were discovered by C. Winkler (1891) in investigating the reducibility of these metals by magnesium. In reducing their oxides by heating them with magnesium powder in a stream of hydrogen, Winkler observed that the hydrogen

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