the rate of progress of a chemical reaction is accelerated by increasing the number of points of contact. It will be enough to point out the fact that sulphuric acid does not absorb ethylene under ordinary conditions of contact, but only after continued shaking, by which means the number of points of contact is greatly increased. To ensure complete action between solids, it is necessary to reduce them to very fine powder and to mix them as thoroughly as possible. M. Spring, the Belgian chemist, has shown that finely powdered solids which do not react on each other at the ordinary temperature may do so under an increased pressure. Thus, under a pressure of 6,000 atmospheres, sulphur combines with many metals at the ordinary temperature, and mixtures of the powders of many metals form alloys. It is evident that an increase in the number of points or surfaces must be regarded as the chief cause producing reaction, which is doubtless accomplished in solids, as in liquids and gases, in virtue of an internal motion of the particles, which motion, although in different degrees and forms, must exist in all the states of matter. It is very important to direct attention to the fact that the internal motion or condition of the parts of the particles of matter must be different on the surface of a substance from what it is inside; because in the interior of a substance similar particles are acting on all sides of every particle, whilst at the surface they act on one side only. Therefore, the condition of a substance at its surfaces of contact with other substances must be more or less modified by them—it may be in a manner similar to that caused by an elevation of temperature. These considerations throw some light on the action in the large class of contact reactions; that is, such as appear to proceed from the mere presence (contact) of certain special substances. Porous or powdery substances are very prone to act in this way, especially spongy platinum and charcoal. For example, sulphurous anhydride does not combine directly with oxygen, but this reaction takes place in the presence of spongy platinum.38
The above general and introductory chemical conceptions cannot be thoroughly grasped in their true sense without a knowledge of the particular facts of chemistry to which we shall now turn our attention. It was, however, absolutely necessary to become acquainted on the very threshold with such fundamental principles as the laws of the indestructibility of matter and of the conservation of energy, since it is only by their acceptance, and under their direction and influence, that the examination of particular facts can give practical and fruitful results.
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