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nydus/The Principles of Chemistry, Volume IPublic

This volume presents a comprehensive overview of chemical principles based on the sixth Russian edition of Dmitry Mendeleyev's work. The text focuses on organizing chemical facts through scientific generalizations, with a particular emphasis on the development and application of the periodic law.

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Table of Contents

CHAPTER I ON WATER AND ITS COMPOUNDS

Water is found almost everywhere in nature, and in all three physical states. As vapour, water occurs in the atmosphere, and in this form it is distributed over the entire surface of the earth. The vapour of water in condensing, by cooling, forms snow, rain, hail, dew, and fog. One cubic metre (or 1,000,000 cubic centimetres, or 1,000 litres, or 35·316 cubic feet) of air can contain at 0° only 4·8 grams of water, at 20° about 17·0 grams, at 40° about 50·7 grams; but ordinary air only contains about 60 per cent. of this maximum. Air containing less than 40 per cent. is felt to be dry, whilst air which contains more than 80 per cent. of the same maximum is considered as distinctly damp.1 Water in the liquid state, in falling as rain and snow, soaks into the soil and collects together into springs, lakes, rivers, seas, and oceans. It is absorbed from the soil by the roots of plants, which, when fresh, contain from 40 to 80 per cent. of water by weight. Animals contain about the same amount of water. In a solid state, water appears as snow, ice, or in an intermediate form between these two, which is seen on mountains covered with perpetual snow. The water of rivers,2 springs, oceans and seas, lakes, and wells contains various substances in solution mostly salt,—that is, substances resembling common table salt in their physical properties and chief chemical transformations. Further, the quantity and nature of these salts differ in different waters.3 Everybody knows that there are salt, fresh, iron, and other waters. The presence of about 3½ per cent. of salts renders sea-water4 bitter to the taste and increases its specific gravity. Fresh water also contains salts, but only in a comparatively small quantity. Their presence may be easily proved by simply evaporating water in a vessel. On evaporation the water passes away as vapour, whilst the salts are left behind. This is why a crust (incrustation), consisting of salts, previously in solution, is deposited on the insides of kettles or boilers, and other vessels in which water is boiled. Running water (rivers, &c.) is charged with salts, owing to its being formed from the collection of rain water percolating through the soil. While percolating, the water dissolves certain parts of the soil. Thus water which filters or passes through saline or calcareous soils becomes charged with salts or contains calcium carbonate (chalk). Rain water and snow are much purer than river or spring water. Nevertheless, in passing through the atmosphere, rain and snow succeed in catching the dust held in it, and dissolve air, which is found in every water. The dissolved gases of the atmosphere are partly disengaged, as bubbles from water on heating, and water after long boiling is quite freed from them.

In general terms water is called pure when it is clear and free from insoluble particles held in suspension and visible to the naked eye, from which it may be freed by filtration through charcoal, sand, or porous (natural or artificial) stones, and when it possesses a clean fresh taste. It depends on the absence of any taste, decomposing organic matter, on the quantity of air5 and atmospheric gases in solution, and on the presence of mineral substances to the amount of about 300 grams per ton (or 1000 kilograms per cubic metre, or, what is the same, 300 milligrams to a kilogram or a litre of water), and of not more than 100 grams of organic matter.6 Such water is suitable for drinking and every practical application, but evidently it is not pure in a chemical sense. A chemically pure water is necessary not only for scientific purposes, as an independent substance having constant and definite properties, but also for many practical purposes—for instance, in photography and in the preparation of medicines—because many properties of substances in solution are changed by the impurities of natural waters. Water is usually purified by distillation, because the solid

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