magnesium chloride. On cooling this solution crystals separate out which contain chlorides of magnesium and potassium. A double salt of this kind, called carnallite , KMgCl 3 ,6H 2 O, occurs at Stassfurt. This carnallite is now employed as a material for the extraction of potassium chloride, and of all the compounds of this element. Besides which, potassium chloride itself is sometimes found at Stassfurt as sylvine . By a method of double saline decomposition, the chloride of potassium may be converted into all the other potassium salts, some of which are of practical use. The potassium salts have, however, their greatest importance as an indispensable component of the food of plants.
The primary rocks contain an almost equal proportion of potassium and sodium. But in sea water the compounds of the latter metal predominate. It may be asked, what became of the compounds of potassium in the disintegration of the primary rocks, if so small a quantity went to the sea water? They remained with the other products of the decomposition of the primary rocks. When granite or any other similar rock formation is disintegrated, there are formed, besides the soluble substances, also insoluble substances—sand and finely-divided clay, containing water, alumina, and silica. This clay is carried away by the water, and is then deposited in strata. It, and especially its admixture with vegetable remains, retain compounds of potassium in a greater quantity than those of sodium. This has been proved with absolute certainty to be the case, and is due to the absorptive power of the soil . If a dilute solution of a potassium compound be filtered through common mould used for growing plants, containing clay and the remains of vegetable decomposition, this mould will be found to have retained a somewhat considerable percentage of the potassium compounds. If a salt of potassium be taken, then during the filtration an equivalent quantity of a salt of calcium—which is also found, as a rule, in soils—is set free. Such a process of filtration through finely divided earthy substances proceeds in nature, and the compounds of potassium are everywhere retained by the friable earth in considerable quantity. This explains the presence of so small an amount of potassium salts in the water of rivers, lakes, streams, and oceans, where the lime and soda have accumulated. The compounds of potassium retained by the friable mass of the earth are absorbed as an aqueous solution by the roots of plants . Plants, as everyone knows, when burnt leave an ash, and this ash, besides various other substances, without exception contains compounds of potassium. Many land plants contain a very small amount of sodium compounds, whilst potassium and its compounds occur in all kinds of vegetable ash. Among the generally cultivated plants, grass, potatoes, the turnip, and buckwheat are particularly rich in potassium compounds. The ash of plants, and especially of herbaceous plants, buckwheat straw, sunflower and potato leaves are used in practice for the extraction of potassium compounds. There is no doubt that potassium occurs in the plants themselves in the form of complex compounds, and often as salts of organic acids. In certain cases such salts of potassium are even extracted from the juice of plants. Thus, sorrel and oxalis, for example, contain in their juices the acid oxalate of potassium, C 2 HKO 4 , which is employed for removing ink stains. Grape juice contains the so-called cream of tartar, which is the acid tartrate of potassium, C 4 H 5 KO 6 . This salt also separates as a sediment from wine. When the plants, containing one or more of the salts of potassium, are burnt, the carbonaceous matter is oxidised, and in consequence the potassium is obtained in the ash as carbonate, K 2 CO 3 , which is generally known as potashes . Hence potashes occur ready prepared in the ash of plants, and therefore the ash of land plants is employed as a source for the extraction of potassium compounds. Potassium carbonate is extracted by lixiviating the ash with water. Potassium carbonate may also be obtained from the chloride by a method similar to that by which sodium carbonate is prepared from sodium chloride. There is no difficulty in obtaining any salt of potassium—for example, the sulphate, bromide, and iodide—by the action of the corresponding acid on KCl and especially on the carbonate, whilst the hydroxide, caustic potash , KHO, which is in many respects analogous to caustic soda, is easily