that the phenomena of this transformation accord with the phenomena of dissociation, and that a fall of temperature should aid the formation of a large quantity of ozone.1 Further, it is evident, from what has been said, that the best way of preparing ozone is not by electric sparks,2 which raise the temperature, but by the employment of a continual discharge or flow of electricity—that is, by the action of a silent discharge.3 For this reason all ozonisers (which are of most varied construction), or forms of apparatus for the preparation of ozone from oxygen (or air) by the action of electricity, now usually consist of sheets of metal—for instance, tinfoil—a solution of sulphuric acid mixed with chromic acid, &c. separated by thin glass surfaces placed at short distances from each other, and between which the oxygen or air to be ozonised is introduced and subjected to the action of a silent discharge.4 Thus in Siemens' apparatus (fig. 37) the exterior of the tube a and the interior of the tube b c are coated with tinfoil and connected with the poles of a source of electricity (with the terminals of a Ruhmkorff's coil). A silent discharge passes through the thin walls of the glass cylinders a and b c over all their surfaces, and consequently, if oxygen be passed through the apparatus by the tube d, fused into the side of a, it will be ozonised in the annular space between a and b c. The ozonised oxygen escapes by the tube e, and may be introduced into any other apparatus.5
The properties of ozone obtained by such a method distinguish it in many respects from oxygen. Ozone very rapidly decolorises indigo, litmus, and many other dyes by oxidising them. Silver is oxidised by it at the ordinary temperature, whilst oxygen is not able to oxidise silver even at high temperatures; a bright silver plate rapidly turns black (from oxidation) in ozonised oxygen. It is rapidly absorbed by mercury, forming oxide; it transforms the lower oxides into higher—for instance, sulphurous anhydride into sulphuric, nitrous oxide into nitric, arsenious anhydride (As 2 O 3 ) into arsenic anhydride (As 2 O 5 ) &c. But what is especially characteristic in ozone is the decomposing action it exerts on potassium iodide. Oxygen does not act on it, but ozone passed into a solution of potassium iodide liberates iodine , whilst the potassium is obtained as caustic potash, which remains in solution, 2KI + H 2 O + O = 2KHO + I 2 . As the presence of minute traces of free iodine may be discovered by means of starch paste, with which it forms a very dark blue-coloured substance, a mixture of potassium iodide with starch paste will detect the presence of very small traces of ozone.