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nydus/The Principles of Chemistry, Volume IPublic
Page 797 of 822
Table of Contents

Hence the store of chemical energy (that is, of the motion of the atoms, vortex, or other) is much greater than the physical store proper to the molecules, but it is the change accomplished by the former that is the cause of chemical transformations. Here we evidently touch on those limits of existing knowledge beyond which the teaching of science does not yet allow us to pass. Many new scientific discoveries have still to be made before this is possible.

10

As if NaH = Mg and KH = Ca, which is in accordance with their valency. KH includes two monovalent elements, and is a bivalent group like Ca.

11

Sodium carbonate and other carbonates of the alkalis give acid salts which are less soluble than the normal; here, on the contrary, with an excess of carbonic anhydride, a salt is formed which is more soluble than the normal, but this acid salt is more unstable than sodium hydrogen carbonate, NaHCO3.

12

The formation of dolomite may be explained, if only we imagine that a solution of a magnesium salt acts on calcium carbonate. Magnesium carbonate may be formed by double decomposition, and it must be supposed that this process ceases at a certain limit (Chapter XII.), when we shall obtain a mixture of the carbonates of calcium and magnesium. Haitinger heated a mixture of calcium carbonate, CaCO3, with a solution of an equivalent quantity of magnesium sulphate, MgSO4, in a closed tube at 200°, and then a portion of the magnesia actually passed into the state of magnesium carbonate, MgCO3, and a portion of the lime was converted into gypsum, CaSO4. Lubavin (1892) showed that MgCO3 is more soluble than CaCO3 in salt water, which is of some significance in explaining the composition of sea water.

13

The undoubted action of lime in increasing the fertility of soils—if not in every case, at all events, with ordinary soils which have long been under corn—is based not so much on the need of plants for the lime itself as on those chemical and physical changes which it produces in the soil, as a particularly powerful base which aids the alteration of the mineral and organic elements of the soil.

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