Owing to this, artificial barium sulphate forms a permanent white paint which is used instead of (and mixed with) white lead, and has been termed ‘blanc fixé’ or ‘permanent white.’ The solution of one part of calcium chloride at 20° requires 1·36 part of water, the solution of one part of strontium chloride requires 1·88 part of water at the same temperature, and the solution of barium chloride 2·88 parts of water. The solubility of the bromides and iodides varies in the same proportion. The chlorides of barium and strontium crystallise out from solution with great ease in combination with water; they form BaCl2,2H2O and SrCl2,6H2O. The latter (which separates out at 40°) resembles the salts of Ca and Mg in composition, and Étard (1892) obtained SrCl2,2H2O from solutions at 90–130°. We may also observe that the crystallo-hydrates BaBr2,H2O and BaI2,7H2O are known.
The nitrates Sr(NO3)2 (in the cold its solutions give a crystallo-hydrate containing 4H2O) and Ba(NO3)2 are so very sparingly soluble in water that they separate in considerable quantities when a solution of sodium nitrate is added to a strong solution of either barium or strontium chloride. They are obtained by the action of nitric acid on the carbonates or oxides. 100 parts of water at 15° dissolve 6·5 parts of strontium nitrate and 8·2 parts of barium nitrate, whilst more than 300 parts of calcium nitrate are soluble at the same temperature. Strontium nitrate communicates a crimson coloration to the flame of burning substances, and is therefore frequently used for Bengal fire, fireworks, and signal lights, for which purpose the salts of lithium are still better fitted. Calcium nitrate is exceedingly hygroscopic. Barium nitrate, on the contrary, does not show this property in the least degree, and in this respect it resembles potassium nitrate, and is therefore used instead of the latter for the preparation of a gunpowder which is called ‘saxifragin powder’ (76 parts of barium nitrate, 2 parts of nitre, and 22 parts of charcoal).